Heater oil production



Jan. 7, 1958 w. A. JUNK, JR., ETAL 2,819,202

HEATER OIL PRODUCTION Filed sept. 2s. 195s Mchn@ i nited States 2,819,202 Haaren orL PnonUc'rloN Application September 28, 1953, Serial No. 382,662

1 Claim. (Cl. 1945-24) This invention relates to the refining of straight run petroleum distillates boiling in the heavier-than-gasoline range. More particularly it relates to the production of a sweet, good color, good copper strip and good burning quality heater oil by the treatment of a sour, high sulfur virgin petroleum distillate boiling between about 300 and 650 F.

A very large demand exists for petroleum distillates which boil in the heavier-than-gasoline range, i. e., within the range between about 300 and 650 F. These disiillates have a tremendous demand for use in domestic heating installations; oils for this purpose are generally known as burning oils, furnace oils, or heater oils. Still another large demand for these distillates is for illumination purposes; oils for this use are generally called kerosene or burning oil. Another large use for oils of this type is as fuels for diesel engines. A rapidly growing use for oils of this type is in the reaction propulsion engine, i. e., jet propulsion; oils for this use are generally called jet fuels or JP-fuels. In general Straight run (virgin) distillates are preferred for these uses. Consumer demand has forced the industry to produce oils of this type which are low in mercaptan-odor, i. e., very low in mercaptan number or even sweet to the Doctor test. Furthermore, consumer demand has forced the industry to produce oils that are of relatively low aromatic hydrocarbon content. At this time the industry is making a greater efiort to produce oils of relatively low total sulfur content, i. e., oils containing on the order of 0.25 weight percent sulfur.

In addition to the requirement for a sweet product of relatively low sulfur content, a demand has arisen for domestic heating oils of improved color and corrosiveness. ln most instances a color of Saybolt is satisfactory. However, highest quality heater oil has a stable color of about Saybolt. The corrosiveness of the oil is measured by a copper strip method; usually a Bolt copper strip number of 3 is satisfactory. However, recently a copper strip of l or even zero has been made a requirement for extra high quality heating oils.

The Doctor process has been used successfully to sweeten these heavy distillates and is being used commercially in spite of the increase in sulfur content of the product oil. The Doctor process for this use has a disability in that the burning quality, as measured by deposits formed in domestic oil burners, is adversely affected.

For many years the burning quality of kerosenes has been improved by an extraction treatment with liquid SO2 in the Edeleaneu process. This treatment removes appreciable amounts of aromatic hydrocarbons and organic sulfur compounds from the raw distillate. The treatment of furnace oils and heater oils with liquid SO2 definitely improves the burning quality thereof, as measured by the deposits in domestic oil burners. However, the SO2 treatment of a sour distillate does not produce a sweet product even though the mercaptan number is usually decreased by the SO2 treatment.

H. S. Seelig, C. E. Johnson and I. F. Deters in Serial No. 322,756, led November 26, 1952, now Patent No. 2,726,989, entitled Heater Oil Production, have set out a combination process which produces a substantially "atent O ice sweet oil of good color stability, good burning quality and a copper strip number of 2-3.

Seelig, et al. discovered that sour distillates can be sweetened by contacting them with an amount of liquid SO2 in excess of the solubility of SO2 in the liquid distillate under the conditions of contacting, in the presence of an effective amount of a sweentening agent, selected fromv the group consisting of free-chlorine, Clz; sulfuryl chloride, $02012 and thionyl chloride, SOC12. However, a sweet oil produced in this manner does not have a satisfactory color stability. A sweet oil having good color stability and satisfactory corrosiveness, i. e., 2-3 copper strip number, can be prepared in a stepwise process by contacting the sour distillate with enough liquid SO2 to form separate raflinate and extract phases, in the presence of about the minimum amount of sweetening agent needed to obtain substantial sweetness, for a short contacting time. ln the second step the raffinate phase from the sweetening step is extracted with suliicient liquid SO2, in the absence of additional sweetening agent, to produce separate raffinate and extract phases. The second railinate phase may be extracted with liquid SO2 alone in a third step, if desired. The product oil derived by the removal of occluded and dissolved SO2 from the second (or third) raflinate phase is sweet, of good color stability, and of satisfactory corrosiveness to copper.

The use of more than the minimum amounts of sweetening agent needed to obtain a sweet productoil results in a product oil that is excessively corrosive. This oversweetened oil can be made of satisfactory copper strip number by treating the second raiinate phase as such, or after removing occluded and dissolved SO2, with hot aqueous caustic solution, i. e., treating at a temperature between about and 220 F.

The sweetening agent of Seelig et al. is selected from at least one member of the group consisting of chlorine, sulfuryl chloride and thionyl chloride. The presence of trace amounts reduces the mercaptan content of the raffinate oil. In order to obtain a product oil that is sweet or substantially so, it is necessary to use about 1 mol of chlorine or sulfuryl chloride per mol of mercaptan in the feed oil; or about 1.5 mols of thionyl chloride per mol of mercaptan in the feed oil. The exact amount of sweetening agent needed to attain a substantially sweet oil varies somewhat depending on temperature, contacting time and contacting efficiency. in general a substantially sweet oil can be obtained with the following quantities of sweetening agent: chlorine or sulfuryl chloride, between about 0.9 and 1.1 mols per mol of mercaptan; thionyl chloride, between about 1.4 and 1.6 mols per mol of mercaptan.

The presence of amounts of sweetening agent in excess of the defined amounts has an adverse effect on the color stability, the copper strip number and the burning quality of the product oil, i. e., if no special treatment is given to overcome this adverse effect. In general it is desirable to use a slight excess of sweetening agent and the adverse effects are then overcome by hot caustic treatment. There is no advantage to using more than about 1.3 mols of chlorine or sulfuryl chloride.

The time of contacting of the feed oil, liquid SO2 and sweetening agent must be sufficiently long to complete the sweetening reaction. However, prolonged contacting beyond the time needed for sweetening has an extremely adverse elect on the copper strip number of the product oil. At the temperatures of operation the product oil will be substantially sweet with 1 or 2 minutes of efficient contacting. The higher the temperature the less time needed. The lower the temperature the more contacting that can be carried out without adverse elfect on copper strip number. In general it is preferred to contact for a time between about 2 minutes and 10 minutes.

The time of contacting of the ratiinate phase containing the sweet oil and the liquid SO2 should be long enough to permit the liquid SO2 to extract the bodies which have an adverse effect on color stability. Prolonged contacting has no adverse effect on the properties of the oil from the liquid SO2 extraction step. Thus contacting times may be between about 2 minutes and 60 minutes.

The temperature of contacting of the feed oil and the liquid SO2 in the presence of sweetening agent in the firststep and with liquid SO2 alone in the second step, or subsequent treatment with liquid SO2 alone, should be below about +70 F. in order to obtain a product oil of good burning quality. Lower temperatures are desirable and temperatures as low as 70 F. may be used. Best results on burning quality and other characteristics of the product oil are obtained 'by operating at a temperature between about +30 and 40 F. Different temperatures may be used in the sweetening step and in the subsequent liquid SO2 extraction step(s).

When the sweetening agent usage has been limited to approximately the amount needed to sweeten the feed oil, the concentration of the aqueous caustic solution and the temperature of aqueous caustic treatment has no appreciable effect on the properties of the product oil. The aqueous caustic solution may contain from about 5 to as much as 50 weight percent of sodium hydroxide or potassium hydroxide. The temperature of aqueous caustic treatment may vary from ambient temperature to about 220 F.

The use of amounts of sweetening agent in excess of about 1.1 mol-s in the case of chlorine or sulfuryl chloride has an adverse effect on the copper strip number and color stability of the product oil. These adverse effects are overcome by treating the final raffinate phase or nal SO2-free raffinate with a concentrated aqueous caustic solution at elevated temperature. By treating at about ambient temperature with aqueous caustic solution containing about 25 weight percent or more caustic, it is possible to obtain a satisfactory copper strip number. At this aqueous caustic concentration it is possible to improve copper strip number and also the color stability by treating at elevated temperatures, preferably at least about 120 F. It may be desirable to operate at temperatures on the order of 220 F.

At least enough aqueous caustic solution should be used to obtain a neutral product oil. The amount of aqueous caustic used may be from between about and 100 volume percent, based on oil.

It is an object of this invention to produce a substantially sweet oil of good color stability, good burning r quality and satisfactory corrosiveness to copper by the treatment of a virgin petroleum distillate boiling in the heavier-tl1an-gasolinc range. A particular object is to produce an oil suitable for use as domestic heating oil, burning oil and jet fuel by the treatment of a straight run petroleum distillate boiling in the range of about 300 to 650 F. Specifically the object of the invention is the treatment of a virgin, sour, high sulfur heater oil in a combination process utilizing liquid sulfur dioxide and a sweetening agent to produce an oil which is substantially mercaptan-free, of good color stability, of good burning quality and of substantially zero copper strip number.

The above objects and other objects not set out in detail are attained as follows: A sour, virgin petroleum distillate boiling in the heavier-than-gasoline range is contacted in the liquid phase in a first zone with sufficient liquid SO2 to form a raffinate phase and a liquid SO2-rich extract phase, in the presence of an amount of a sweetening agent, selected from the group consisting of chlorine, sulfuryl chloride and thionyl chloride in an amount at least sufficient to substantially sweeten said distillate. The contacting in the first zone is carried out at a temperature below about +70 F. for a time suicient to substantially sweeten the distillate. The raffinate phase from the first zone is contacted in the liquid phase in a second zone at a temperature below about |70 F. with enough liquid SO2 to yform a second raffinate phase and an extract phase. The second raffinate phase is processed to remove occluded and dissolved SO2, preferably by treatment with aqueous caustic solution. The sweet oil is then maintained at a temperature between about and 300 F. for a time sufficient to obtain a copper strip number of not more than about l.

The petroleum distillates charged to tbe process boil in the heavicr-than-gasoline range and are derived by distillation of crude oil and are commonly known as straight run or virgin distillates. In general the heavierthan-gasoline boiling range distillates boil within the range of about 300 to 650 F. The process is particularly suitable for the refining of those distillates which are high in sulfur content, i. e., distillates which contain more than about 0.3 weight percent sulfur. A preferred feed stock is a sour, high sulfur straight run petroleum distillate which boils within the range of about 350 to 625 F. High sulfur crudes such as West Texas and California crudes provide distillates which are particularly suitable for treatment by this process.

The process of this invention is described in conjunction with the annexed drawing which forms a part of this specication and shows in schematic form one embodiment of the process of this invention. It is to be understood that many items of process equipment have been omitted as these may readily be added by those skilled in the art.

ln the drawing sour distillate feed from source 11 is passed through line 12 into a deaeration unit 13. The feed stock in this illustration is a virgin heater oil derived from the distillation of West Texas crude, which oil has a mei-captan number of 70 and a sulfur content ot' about 0.7%, a phenol content of 0.2%, and an A. S. T. M. boiling range between about 330 and 550 F.

When operating with feed oils of very high viscosity and/or comparatively high solid points, the feed oil may be diluted with a low freezing point, low viscosity oil which can be readily separated from the product oil by distillation. Examples of suitable diluent oils are butane, peutane, hexane.

Deaeration unit 13 may comprise conventional equipment such as the vacuum deaeration equipment ordinatily employed in commercial processes of liquid SO2 refining of hydrocarbon oils. The deaerated feed is passed from deaerator 13 through line 14 into drying zone 16. Water is harmful to the extraction process and it is preferred that the feed oil be substantially dehydrated. Drying zone 16 may comprise conventional equipment and drying reagents, e. g., drier 16 may be a vessel packed with calcium chloride, roel: salt, magnesium silicate, alumina gel, etc. In some instances it may be desirable to dehydrate by means of vacuum distillation. it is to be understood that the specific form of deacrator 13 and drier 16 is no part of the present invention and that any treatment may be used which substantially eliminates air and water from the feed.

The oil from drier 16 is passed through line 17 and through heat exchanger 18 where the temperature of the oil is lowered to the desired operating temperature, herein -10 F.

It is preferred to carry out the sweeteuing and liquid u SO2 extraction steps in a continuous countercurrent extraction tower. By the use of a tower the liquid S0?4 usage is minimized for a product oil of good quality. In a countercurrent tower the total liquid SO2 may be introduced at an upper point in the tower, e. g., .near the top thereof; the feed oil may be introduced at a lower point in the tower, e. g., near the bottom thereof; and the sweetening agent may be introduced at an intermediate point, e. g., near the vertical midpoint of the tower; or the sweetening agent may be introduced at `several points along the height of the tower. In any event, at least .one theoretical extraction stage should be present in the tower for the contacting of the feed oil with liquid SO, and sweetening agent. At least one theoretical extraction stage should be available for the contacting of the substantially sweet raffinate phase with liquid SO2, in the absence of additional sweetening agent.

The cold oil is passed through line 19 into a lower portion of extractor 21. Extractor 21 is a tower packed with suitable materials in order to increase the efficiency of contacting of the feed and the liquid SO2. For example, extractor 21 may be packed with Berl saddles, glass, or metal spheres, alumina balls, jack chain, etc. Also, extractor 21 may be in the form of a bubble tower which has been arranged for extraction purposes. Extractor 21 may also be provided with mechanical agitators arranged along the height of the column to improve agitation. Extractor 21 may also be provided with heat exchangers to permit control of the temperature of contacting or to permit operation with a temperature gradient Within the tower.

Liquid SO2 from source 22 is passed through valved line 23 into an upper portion of extractor 21. In the sweetening step and the liquid SO2 extraction step, the liquid SO2 must be present in an amount at least sufficient to produce separate raiiinate and extract phases. This minimum amount will vary with the temperature of contacting. In general 20 volume percent of liquid SO2, based on charge to the contacting, will produce distinct railinate and extract phases at the preferred temperatures of operation. More than this minimum amount is preferred, and amounts as much as 500 volume percent, may be utilized. It has been found that very little improvement in burning quality is obtainable by using very large amounts of liquid SO2 even though the yield of product oil is markedly decreased. It is preferred to operate with the liquid SO2 lusage between about 20 and 8O volume percent, based on charge.

The extraction must be carried out under liquid conditions and sufcient pressure must be applied to extractor 21 in order to maintain the SO2 in the liquid phase. ln this illustration the total amount of liquid SO2 used is 75 volumes per 100 volumes of feed oil. At least one theoretical extraction stage is present in the upper zone of extractor 21 and the contacting time therein is about 3 minutes.

The contacting in the sweetening step and liquid S02 extraction step may be carried out batchwise in one or more separate stages; for example, in a batchwise operation, part of the sweetening agent may be introduced in a first stage along with liquid SO2 and the remainder of the sweetening agent introduced in a second stage along with liquid SO2. A separation of a rafnate phase from an extract phase may be made between each of the sweetening stages and the rainate phase alone sent to the second sweetening stage; or the total material from the first stage may be sent to the second stage, in which case additional liquid SO2 may or may not be added. The liquid SO2 extraction of the sweet raffinate phase from the sweetening step may be carried out in one, two or more separate steps, preferably with a separation of raffinate phase from extract phase between each step.

When the process of this invention is being carried out in batch stages, sufficient liquid SO2 must be added in. each stage to produce separate raiiinate and extract phases, and preferabiy the usage should be between about 20 and 80 volume percent, based on charge to the particular stage. When the process is being carried out in a countercurrent tower, the liquid SO2 usage should be at least enough to produce distinct raffinate and extract phases. It is preferred to operate with between about 20 and S0 volume percent of liquid SO2, based on feed oil charged to the tower.

Although chlo-rine gas reacts with SO2 to form sulfuryl chloride, it has been found that the chlorine content of the product oil when using chlorine as the sweetening agent is higher than when using sulfur'yl chloride as the sweetening agent. It is preferred to use sulfuryl chloride as the sweetening agent. In this embodiment 1.3 mols of sulfuryl chloride are used per mol of mercaptan in the feed. The sulfuryl chloride from source 24 is passed through line 25 into extractor 21 at about the vertical mid-point of extractor 21. If preferred the sulfuryl chloride could be introduced at various points along the height of the tower. lt is necessary to provide at least one theoretical extraction stage above the last point of suifuryl chloride introduction and the exit of the extractor. Herein an excess of sulfuryl chloride is used in order to insure sweetening with a relatively short contact time of 3 to 4 minutes in the lower sweetening zone of the extractor. lt is preferred to maintain the interface somewhat above the point of entry of the sulfuryl chloride, but below the point of entry of the liquid sulfur dioxide.

From the bottom of extractor 21 an extract phase is removed and is passed through line 26 into stripper 27 which is equipped with a reboiler 28. In stripper 27 the SO2 is removed from the extract and is taken overhead through line 29. A substantially SO2-free extract is removed from stripper 27 through line 31 and is sent to storage not shown.

The raffinate phase is removed from extractor 21 through line 33 and is passed into stripper 34 which is provided with reboiler`36. In stripper 34 most of the occluded and dissolved S02 is removed overhead by way of line 37 and is passed into line 29.

In the course of operation some impurities such as water and H28 pass into the SO2 and these should be removed before the SO2 is recycled to the process. The contaminated SO2 in line 29 is passed into purification zone 38 where the impurities are removed. The purified SO2 is passed through line 39 into line 23 and is reused in extractor 21. Purication zone 38 is shown schematically and may be any conventional equipment such as is used in liquid SO2 refining of hydrocarbon oils.

The substantially SO2-free raihnate oil is removed from stripper 34 by way of line 41 wherein it meets a stream of aqueous caustic solution. Aqueous caustic solution containing 30 weight percent NaOH is passed from source 42 through line 43, heat exchanger 44 and line 45 into line 41. The aqueous caustic solution is raised to a temperature of about 225 F. in heat exchanger 44. The mixture in line 41 is passed into mixer 46 wherein the oil and aqueous caustic are thoroughly intermingled in order to neutralize the SO2 remaining in the oil and remove bodies deleterious to copper strip number and color stability. Mixer 46 is provided with a heating coil 47 which maintains the contents of the mixer at a temperature of about 225 F. In this embodiment about 35 volume percent of aqueous caustic solution is used per volume of oil in line 41.

The mixture of oil and aqueous caustic is passed through line 49 into settler 51 Where two phases separate. 'I he lower aqueous caustic phase is removed from settler S1 by way of line 52 and is sent to spent caustic disposal. The aqueous caustic may be recycled by way of valved line 53 to line 43 for reuse in the treating. The neutralized oil is withdrawn from settler 51 by way of line 56.

When the sweet oil is heat treated the method of removing occluded and ldissolved SO2 from the iinal raffinate phase to produce a neutral product oil is of little moment in regard to the properties of the product oil, i. e., the dissolved and occluded SO2 can be completely removed by stripping with an inert gas such as propane or nitrogen; or the S02 may be weathered away by heating to a moderate temperature for a period of time, or the SO2 may be removed by treatment with aqueous NaOH or KOH solution; or preferably a combination of stripping and aqueous caustic treating. In the case of the SO2C12 sweetening agent, the maximum usage without harmful effect is about 1.1 mols per mol of mercaptan.

The temperature of contacting and the concentration of caustic in the aqueous caustic neutralization step may vary from ambient atmosphere to 300 F. or higher. The aqueous caustic contacting step may be carried out at a temperature above about 100 F. in order to reduce the amount of time needed in the subsequent heat treatment to produce a sweet oil of not more than about l copper strip number; and this mode of operation is preferred.

The hot oil from line 56 is passed into .the lower portion of coalescer S7. Coalescer 57 is a vertical cylindrical vessel provided with a bed of gravel, sand, fiberglass, steel wool, etc. The coalesced aqueous caustic particles are withdrawn from coalescer S7 by way of line 58 to waste disposal.

The dehazed sweet oil is passed by way of line 6l into trcatcr 62. Treater 62- is a large vessel, for example, a storage tank, provided with insulation 64 and heating means 66. The sweet, neutral oil is maintained in treater (r3 at a temperature between about 150 and about 300 F. ter a time sufficient to obtain an oil having a copper strip number of not more than about l, preferably about i' e." The heat treatment varies with the tenperature and the copper number of the oil charged to the heat treatment. In general, the time to obtain a strip of l will vary .from about 24 hours at about 150 F, to about l hours at 250 F. Additional time will be needed when a zero strip is desired; at the lower temperatures, this time may be unreasonably long. It is preferred to operate at a temperature between about 200 and 250 F. for a time of at least about l0 hours. The oil in treater 62 is maintained at a temperature of 225 F. for a total treating time of 24 hours in order to obtain a copper strip of 0+. Product oil is passed through line 60 to storage not shown.

The results obtainable by the process of this invention are illustrated below. In these experiments the raw oil was contacted with liquid SO2 and sweetening agent or liquid SO2 alone in a glass reaction vessel provided with a 10,000 R. P. M. stirrer. The raw oil was introduced into the vessel and the liquid SO2 was added and the contents brought to a temperature of 4 F. Then the desired amount of SU2Cl2 was added to the reaction vessel and contacted for 5 minutes. After the contacting the contents were settled and the separate raffinate and extract phases withdrawn.

The ratiinate phase from the sweetening step was then contacted with liquid SO2 in the reaction vessel at -4 l?. for 5 minutes. The separate phases from this second contacting step were withdrawn and the second raffinate phase, was given another contacting with liquid SO2 at 4 F. The liquid SO2 usage in each stage was 50% based on oil.

The three-stage batch countercurrent contacting as described above is about the equivalent of a countercurrent contacting using about one-halt the liquid SO2 used in the batch contacting.

The raw oils used in these experiments were derived by distillation from a West Texas crude. Each of the feed oils lies in the so-called heater oil classication. The physical characteristics of the feed oils are given in T able l.

o ASTM Dis"illation-F.:

IB l

The corrosiveness of an oil is determined by its elect on the color of a copper strip. The copper strip corrosion is determined for heater oil by immersing a copper strip in the oil for 3 hours at 212 F. The corrosiveness of the eil in this specification has been determined by the Bolt copper strip number technique. This technique is described in the August 9, 1947, issue of the Oil and Gas Journal. In this method the number 0 is assigned to a perfect strip, i. e., equal to a strip prior to being used in a test. The higher the number assigned to a strip after tbe test, the more corrosive the oil.

Test Z in this test the eicct of variation in the temperature of aqueous caustic contacting was determined when treating feed A in all runs 1.0 mol of S0202 were used per :uol of mui-captan in the sour oil. The ratnate oil from the :cond liquid SO2 contacting step was treated with 50 volume percent of aqueous NaOH solution. The neutral oil was held for 20 hours at 200 F. The results of this These data indicate that the temperature and/or con centration of aqueous caustic in the neutralization step has no appreciable effect on the copper strip number of the heat treated oil.

Test 2 In this test, the relationship of temperature of heat treatment and time was determined on feed B. The SO2Cl2 usage was 1.3 mols per mol of mercaptan and a 10% aqueous NaOH solution was used to neutralize the extracted oil at 104 F. The neutral oil was sweet, had a Saybolt color of +30 and a copper strip number of 3. The results of these runs are given in Table Hl.

TABLE III Treated Oil Heut 'lroatmont,

Hours F 200 F. 250 F.

Copper Color Copper Color Copper Color Strip Strip Strip 3 +30 +30 3 +30 3 +27 f Eil 2 tf) 2 +24 2 ('l 3 +24 1 t) l t) 2 +25 I V) l ('l l +24 0 i C) *Estimated to be +20 or better.

The data indicate that temperatures above 150 F. are desirable in order to decrease the treating time. Also that a zero copper strip can be obtained by heat trcating the oil for a sutlicient time. This improvement in copper strip is obtained without a signicant loss of color.

Thus having described the invention, what is claimed is:

A process for refining a high-sulfur, sour virgin heater oil boiling between about 350 and 625 F., which process comprises (l) contacting said oil with about 50 volume percent, based on said oil, of liquid SO2 in the presence of about l.3 mols of sulfuryl chloride per mol of mercaptans in said oil, for about S minutes at a temperature of about F., (2) separating an extract phase from a ranate phase, (3) contacting said raiinate phase with about 50 Volume percent of liquid SO2, based on said ratinate phase, at a temperature of about 0 F. for about 5 minutes, (4) separating a second extract phase from a second raffinate phase, (5) contacting said second rafnate phase with about 50 volume percent of liquid SO2, based on said second ranate phase, at a temperature of about 0 F. for about 5 minutes, (6) separating a third raflnate phase from a third extract phase, (7) stripping substantially all of the SO2 from the rainate phase of step (6), (8) treating the stripped rainate phase With aqueous caustic containing between about 10 and about weight percent of NaOH, at a temperature of between about and 300 F., (9) separating a neutralized oil from an aqueous phase, (10) removing aqueous haze from the oil of step (9), and (11) heat treating said oil in the liquid state from step (10) at a temperature between about 200 F. and 250 F. for a time of at least about 10 hours, said heat-treated oil characterized by. a copper strip number of not more than about 1.

References Cited in the file of this patent UNITED STATES PATENTS 

